Solvent-less Oxidation of Aromatic Alcohols Using CrO3/Al2O3 under Ultrasonic Irradiation

نویسندگان

چکیده

Alcohol oxidation plays an essential contribution to the chemical industry. Innovative green techniques, such as ultrasound irradiation, could be economically remarkable by enhancing reaction yield. In this research, design and improvement of a new ultrasound-assisted alcohols procedure using CrO3 supported Al2O3 with addition small amount t- butanol were reported. The was also done without irradiation study sonochemical effect. Based on FTIR GC/MS analyses, effectively oxidized into their corresponding aldehydes in satisfactory yields (74–93%). yield obtained increased applying ultrasonic technique, no over-oxidation products found. Overall, innovative offers several benefits, being easy use, environmentally friendly, capable improving yields, having shorter times.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of Metallophthalocyanines Under Solvent Free Conditions Using Microwave Irradiation

Phthalocyanine complexes of Cu, Co, Ni, Fe, Zn, Pd, Pt and Ru have been synthesized from reaction between phthalonitrile and proper metal salts upon exposure to microwave irradiation under solvent-free conditions and considerably reduced reaction times.

متن کامل

synthesis of metallophthalocyanines under solvent free conditions using microwave irradiation

phthalocyanine complexes of cu, co, ni, fe, zn, pd, pt and ru have been synthesized from reaction between phthalonitrile and proper metal salts upon exposure to microwave irradiation under solvent-free conditions and considerably reduced reaction times.

متن کامل

synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides

کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...

15 صفحه اول

Solvent free oxidation of primary alcohols and diols using thymine iron(III) catalyst.

In this study, we developed an efficient and selective iron-based catalyst system for the synthesis of ketones from secondary alcohols and carboxylic acids from primary alcohol. In situ generated iron catalyst of thymine-1-acetate (THA) and FeCl(3) under solvent-free condition exhibits high activity. As an example, 1-octanol and 2-octanol were oxidized to 1-octanoic acid and 2-octanone with 89%...

متن کامل

Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(IV) oxide under irradiation of green light.

Gold nanoparticles supported on cerium(IV) oxide powder showing strong absorption at around 550 nm due to surface plasmon resonance oxidized aromatic alcohols to corresponding aldehydes almost quantitatively in an aqueous suspension under irradiation of green light.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Jurnal Kimia Sains dan Aplikasi

سال: 2022

ISSN: ['1410-8917', '2597-9914']

DOI: https://doi.org/10.14710/jksa.25.8.280-285